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- YAMAZOE Sayumi
- Graduate School of Life and Environmental Sciences, University of Tsukuba Institute for Chemical Research and Institute for Integrated Cell-Material Sciences, Kyoto University
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- HASEGAWA Koji
- Graduate School of Life and Environmental Sciences, University of Tsukuba
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- SHIGEMORI Hideyuki
- Graduate School of Life and Environmental Sciences, University of Tsukuba
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抄録
The first total synthesis of 4-methylthio-3-butenyl glucosinolate (MTBG), a natural bioactive compound and a precursor of radish phototropism-regulating substances, was achieved from commercially available 1,4-butanediol. The glucosinolate framework was prepared by coupling of an oximyl chloride derivative and tetraacetyl thioglucose. A methylthio group was introduced to the framework by a Wittig reaction between triphenylphosphonium thiomethylmethylide and an aldehyde intermediate of glucosinolate. The synthetic route should facilitate preparation of various derivatives needed for probe synthesis based on MTBG.
収録刊行物
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- Bioscience, Biotechnology, and Biochemistry
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Bioscience, Biotechnology, and Biochemistry 73 (3), 785-787, 2009
公益社団法人 日本農芸化学会
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詳細情報 詳細情報について
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- CRID
- 1390001206480028160
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- NII論文ID
- 10027539345
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- NII書誌ID
- AA10824164
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- ISSN
- 13476947
- 09168451
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- NDL書誌ID
- 10199529
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 使用不可