トリウムの電解精製過程における不純物の挙動

書誌事項

タイトル別名
  • Behaviors of Impurities in the Electrorefining Process of Thorium Metal
  • トリウム ノ デンカイ セイセイ カテイ ニ オケル フジュンブツ ノ キョドウ

この論文をさがす

抄録

In order to see the separation efficiency of the high temperature electrorefining of thorium, mixtures of thorium and other metals were electrorefined in a fused salt bath containing sodium and potassium chlorides. In these experiment, radioactive tracers were used to estimate the micro-quantities of these elements. Cobalt and lead, which have lower reversible decomposition voltage, can be thoroughly eliminated as anode slime. And the contents of these elements in the cathode deposites were about 10−10%. Titanium, zirconium and uranium, which have only a few tenth volt of difference, were also separated fairly well. Rare earth elements, which have high absorption cross section for thermal neutron, can also be removed in this process, because the electrode potentials of these elements are rather high. Activation analysis by neutron irradiation showed that the refined thorium contained less than 5 ppm of Dy and Sm.

収録刊行物

  • 日本金属学会誌

    日本金属学会誌 23 (7), 393-397, 1959

    公益社団法人 日本金属学会

被引用文献 (1)*注記

もっと見る

詳細情報 詳細情報について

問題の指摘

ページトップへ