Studies on Thermodynamic Properties of Co<SUB>3</SUB>B and Co<SUB>2</SUB>B by e.m.f. Measurements

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  • 起電力法によるCo<SUB>3</SUB>BおよびCo<SUB>2</SUB>Bの熱力学的性質の研究
  • 起電力法によるCo3BおよびCo2Bの熱力学的性質の研究
  • キデンリョクホウ ニヨル Co3B オヨビ Co2B ノ ネツリキガクテキ セ

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The e.m.f. measurements were made on the cell,<BR>(This article is not displayable. Please see full text pdf.) <BR>\oindentby using a Co-B alloy containing about 20 at%B. The e.m.f. values were used in calculation of the thermodynamic properties of Co3B and Co2B. The calculated thermodynamic properties are as follows:<BR>(This article is not displayable. Please see full text pdf.) <BR>\oindentand<BR>(This article is not displayable. Please see full text pdf.) <BR>\oindentIn the diagram of the e.m.f. vs temperature, the intersection of a line for the system Co+Co3B with a line for the system Co+Co2B yielded a eutectoidal temperature of 845°C.

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