Density of LiCl-NaCl-AlCl<SUB>3</SUB> Ternary Melt

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  • 溶融LiCl-NaCl-AlCl<SUB>3</SUB> 3成分系の密度
  • 溶融LiCl-NaCl-AlCl33成分系の密度
  • ヨウユウ LiCl NaCl AlCl3 3セイブンケイ ノ ミツド

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Density of LiCl-NaCl-AlCl3 ternary melt has been measured over the composition range of less than 50 mol%AlCl3 and the temperature range of 800∼1200 K by means of the manometric method using a special electric furnace whose inside can be seen through. The results obtained are summarized as follows :<BR>The density of the ternary melt was expressed as a function of temperature and composition on the basis of the data measured. The density decreases with an increase in LiCl or AlCl3 content, and the degree of the decrease depends largely on the change in AlCl3 rather than LiCl content.<BR>The ternary melt of the composition range of less than 50 mol%AlCl3 was regarded as a reciprocal melt of (Li+,Na || Cl−,AlCl4−) because most of the aluminum chloride exists as AlCl4− anionic species in this composition range. The molar volume and the expansion coefficient of the reciprocal melt, and the partial molar volumes of the compounds LiC1, NaCl, LiAlCl4, NaAlCl4 were calculated. The molar volume increases with an increase in either the cationic fraction of Na+ or the anionic fraction of AlCl4−. The expansion coefficient depends on the anionic fraction rather than the cationic fraction. The partial molar volume of each compound slightly increases with the change of the cationic fraction, and decreases with the change of the anionic fraction.<BR>These results could be explained in terms of the size and the electrical charge density of ionic species and the hole volume of the compounds.

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