撹拌槽内における酸化第二鉄の塩酸水溶液による浸出速度

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タイトル別名
  • Leaching Rate of Hematite in Hydrochloric Acid Solutions in Agitated Vessel
  • 攪拌槽内における酸化第2鉄の塩酸水溶液による浸出速度
  • カクハンソウナイ ニ オケル サンカ ダイ 2 テツ ノ エンサン スイヨウエ

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A kinetic study on the leaching of Fe2O3 in HCl solutions has been made by using agitated vessel to clarify the machanism of the rate acceleration which was found in the previous study for Fe2O3-HNO3 system. Powder specimens with various sizes were prepared by a wet classification of ground powder obtained from pellets sintered at 1623 K (I) and 1523 K (II). The specific areas of these specimens were measured before and after the leaching experiments. Leaching rates were found to be independent of the agitation speed. Leaching rates under various conditions were correlated by the following relationship:<BR>(This article is not displayable. Please see full text pdf.) <BR>\oindentwhere α is the fraction dissolved, Sw0 the initial specific area of the specimen, T temperature, C concentration of ionic species. As seen in the above correlation, the leaching rate increased with increasing α. In order to clarify the mechanism of the rate acceleration, a leaching experiment was carried out by using a sintered Fe2O3 disk of which surface was polished and exposed to a HCl solution. Same as the previous study, only the (0001) oriented crystal planes were found to dissolve and its dissolution rate increased with time. The fractional area of the (0001) plane was about 25%. Assuming the same fractional area for the powder specimen, the increase in the overall surface area was well estimated.

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  • 日本金属学会誌

    日本金属学会誌 58 (3), 297-302, 1994

    公益社団法人 日本金属学会

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