SiC被覆C/C複合材料の高温酸化挙動

書誌事項

タイトル別名
  • High Temperature Oxidation Behavior of SiC-Coated C/C Composites
  • SiC ヒフク CC フクゴウ ザイリョウ ノ コウオン サンカ キョドウ

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説明

High-temperature oxidation behavior of the SiC-coated Carbon/Carbon (C/C) composites was examined in the temperature range between 873 and 2273 K under open air environment. From the oxidation tests, three kinds of oxidation regimes were identified: i.e., oxidation reaction rate controlling regime; 873 K to 1173 K, oxygen diffusion controlling regime; 1173 K to 1973 K, and SiC sublimation regime; above 1973 K. Weight loss below 1973 K was due to the oxidation of the C/C substrate by oxygen diffusion through coating cracks. To understand the oxidation behavior, a morphological characterization of coating cracks has been done from the results of the microscopic observation of SiC coating. In particular, in the oxygen diffusion controlling temperature range, an analytical model was developed for the prediction of weight loss due to oxidation of the SiC-coated C/C composites. This model was derived from considering the oxygen diffusion in the coating cracks with the aid of statistical information on coating cracks, such as the distribution and temperature dependence of the coating crack width. Furthermore, considering the effect of silica growth at the crack walls during the oxidation, the weight loss curves were also predicted as a function of oxidation time. The oxidation rate and weight loss curves derived from this model are in fairly good agreement with the experimental results.

収録刊行物

  • 日本金属学会誌

    日本金属学会誌 62 (4), 404-412, 1998

    公益社団法人 日本金属学会

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