水素処理によるNb-Cr合金粉末の作製

書誌事項

タイトル別名
  • Preparation of Nb-Cr Alloy Powder by Hydrogenation
  • スイソ ショリ ニヨル Nb Cr ゴウキン フンマツ ノ サクセイ

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抄録

The pulverization by hydrogenation is a new method for fabricating intermetallic powders with high quality and low cost. In this study, the pulverization by hydrogenation was studied for various Nb-Cr alloys. The hydrogenation was performed under the hydrogen atmosphere of 0.1 MPa in an arc-melting chamber without exposure to air after arc-melting. Constituent phases and lattice constants before and after hydrogenation were examined by X-ray diffraction analysis. It is found that the pulverization by hydrogenation occurs only in two phase alloys consisting of Nb solid solution (Nbss) and NbCr2. In the Nbss/NbCr2 alloys, the lattice constant of Nbss increases remarkably through hydrogenation, while that of NbCr2 does not change. It is concluded that the pulverization of the Nbss/NbCr2 two phase alloy is caused by large strain accompanied with lattice expansion of Nbss through hydrogenation and crack nucleation at intrinsically brittle NbCr2.

収録刊行物

  • 日本金属学会誌

    日本金属学会誌 62 (7), 681-689, 1998

    公益社団法人 日本金属学会

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