Multiple Alkylation of Thiophene Derivatives with Simple and Extended Diarylcarbenium Ion Pools

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  • NOKAMI Toshiki
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University Present address: Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University
  • WATANABE Takashi
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University
  • TERAO Kimitada
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University
  • SOGA Kazuya
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University
  • OHATA Kousuke
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University
  • YOSHIDA Jun-ichi
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University

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抄録

The reactions of thiophene derivatives, bithiophene, and terthiophene with an electrochemically generated diarylcarbenium ion pool afforded multiple alkylation products. Extended diarylcarbenium ion pools afforded dendritic molecules by the multiple alkylation of bithophene and terthiophene.

収録刊行物

  • Electrochemistry

    Electrochemistry 81 (5), 399-401, 2013

    公益社団法人　電気化学会

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