Cellular Automata for Electrochemistry. A Practical Approach to the Understanding of Voltammograms

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  • HAYASHI Shigeo
    Department of Engineering Science, University of Electro-Communications

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Abstract

One-dimensional multicomponent cellular automata, with the addition of a reactive boundary, can model electrochemical processes such as cyclic voltammetry. Electron transfer probabilities at the boundary are derived from the Butler-Volmer type kinetic equation. The model is applied successfully to coupled irreversible systems in which an escaping species is involved in addition to oxidized and reduced species.

Journal

  • Electrochemistry

    Electrochemistry 81 (1), 16-18, 2013

    The Electrochemical Society of Japan

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