High Rate Charge and Discharge Characteristics of Graphite/SiOx Composite Electrodes
-
- YOSHIDA Shuhei
- DENSO CORPORATION Department of Molecular Chsmitry and Biochemistry, Doshisha University
-
- OKUBO Takashi
- Department of Molecular Chsmitry and Biochemistry, Doshisha University
-
- MASUO Yuta
- Department of Molecular Chsmitry and Biochemistry, Doshisha University
-
- OBA Yasuyuki
- DENSO CORPORATION
-
- SHIBATA Daisuke
- DENSO CORPORATION
-
- HARUTA Masakazu
- Department of Molecular Chsmitry and Biochemistry, Doshisha University
-
- DOI Takayuki
- Department of Molecular Chsmitry and Biochemistry, Doshisha University
-
- INABA Minoru
- Department of Molecular Chsmitry and Biochemistry, Doshisha University
書誌事項
- タイトル別名
-
- High Rate Charge and Discharge Characteristics of Graphite/SiO<i><sub>x</sub></i> Composite Electrodes
この論文をさがす
説明
Charge and discharge properties of a graphite/SiOx composite electrode were studied over a wide range of charge/discharge rates (1/20 to 5 C) for use in automotive applications. The graphite/SiOx (90/10 by weight) composite electrode gave a high reversible capacity (453 mAh·g−1), and showed a good capacity retention at a low rate of 1/20 C. However, the capacity decreased significantly on cycling at a high rate of 2 C. From the analysis of the charging and discharging processes, it was found that the charging reaction occurs predominantly at SiOx particles initially at higher potentials and then proceeds at graphite particles at lower potentials to be fully charged. This tendency was also supported by a dependence of the activation energy of the charge transfer reaction on the state of charge (SOC) estimated by ac impedance analysis. Because the composite electrode contains only 10% SiOx, the current was excessively concentrated to the SiOx particles at the initial state when charged at high rates. This caused crack formation in SiOx particles, and the resulting contact loss between particles was considered as the reason for the observed poor cycleability at 2 C.
収録刊行物
-
- Electrochemistry
-
Electrochemistry 85 (7), 403-408, 2017
公益社団法人 電気化学会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390001206499408128
-
- NII論文ID
- 130007342810
-
- NII書誌ID
- AN00151637
-
- ISSN
- 21862451
- 13443542
-
- NDL書誌ID
- 028325904
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用可