不飽和二塩基酸誘導体の合成, 重合に関する研究

DOI 被引用文献4件

書誌事項

タイトル別名
  • Syntheses and Polymerization of Unsaturated Dibasic Acid Derivatives
  • IX. Copolymerization of N-(4-substituted phenyl) Maleimides
  • 第9報N-(4-置換フェニル) マレイミド類の共重合

抄録

The copolymerization of N-(4-substituted phenyl) maleimide (M2) with vinyl acetate (M1) by radical initiator was carried out, and the effects of substituents of N-(4-substituted phenyl) maleimides on the copolymerization reaction were investigated. While, as for the relative reactivities (1/r1) of N-(4-substituted phenyl) maleimides toward vinyl acetate radical, no reasonable order was obtained through the all substituents, the 1/r2 decreased in the following order of the substituents COCH3>COOC2H5>OCOCH8>Cl>H>CH3>OCH3.<BR>The order can mostly be explained in term of polar effect and difference in homopolymerization reactivity.<BR>Linear relationships between Hammett's σ values and the 1/r2 values, and also between σ and the e2 values werefound, and these results were discussed.

収録刊行物

  • 高分子化學

    高分子化學 23 (253), 348-353, 1966

    公益社団法人 高分子学会

被引用文献 (4)*注記

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詳細情報 詳細情報について

  • CRID
    1390001206519262720
  • NII論文ID
    130004032601
  • DOI
    10.1295/koron1944.23.348
  • ISSN
    18848079
    00232556
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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