Studies on Hardening of Amino Resins
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- Nakajima Mikio
- Nippon Carbide Industries Co., Inc., Tokyo Research Laboratory
Bibliographic Information
- Other Title
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- アミノ樹脂の硬化に関する研究
- III. Relations between the Degree of Cure of Melamine-Formaldehyde Resin and the Curing Conditions, and Kinetics of Condensation at C-Stage
- 第3報メラミン樹脂の硬化度と硬化条件の関係およびC-Stageにおける硬化の動力学
Abstract
The relations between the degree of cure (the value obtained by “formaldehyde isolation test”) and the curing conditions were studied on melamine-formaldehyde resin laminates.<BR>The rate equation for hardening of resin in C-stage was proposed and the apparent activation energy was ca. 20.5 kcal/mol.<BR>Further, the effect of catalyst on curing temperature and time was studied quantitatively.<BR>Main experimental equations were shown below.<BR>The notations are<BR>F: degree of cure (mg/100cm2)<BR>T, (Tc): curing temperature (°K), (when using catalyst)<BR>t, (tc): curing time (min), (when using catalyst)<BR>C: catalyst added in varnish (%) a, a′, a″, k1, k1′, k1″, k2, k2′, k2″, α, β, γ, δ, to: const.
Journal
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- Kobunshi Kagaku
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Kobunshi Kagaku 21 (233), 544-552, 1964
The Society of Polymer Science, Japan
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Details 詳細情報について
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- CRID
- 1390001206519669632
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- NII Article ID
- 130004032475
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- ISSN
- 18848079
- 00232556
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- Text Lang
- ja
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed