不飽和二塩基酸誘導体の重合に関する研究

DOI 被引用文献1件

書誌事項

タイトル別名
  • Polymerization of Unsaturated Dibasic Acid Derivatives
  • III. Syntheses and Polymerization of Alkyl Vinyl Maleates and Fumarates
  • 第3報マレイン酸ならびにフマル酸のアルキルビニルエステルの合成, 重合について

抄録

Ethyl-, n-propyl-, i-propyl and n-butyl vinyl maleates and fumarates were synthesised bythe vinyl interchange reaction of vinyl acetate with mono alky maleates, and the physicalproperties of these compounds were determined.<BR>With radical initiator, the highest rate of polymerization was obtained with the i-propylester.<BR>Percent cyclization of the polymerization products was measured by infrared spectroscopy.<BR>The poly maleates showed high 4-membered ring contents and lower 5-membered ring contents.In poly fumarates only a small amount of 5-membered ring was found to be formed.<BR>The observed difference in cyclization behavior in the two series of polymer was discussed.

収録刊行物

  • 高分子化學

    高分子化學 20 (215), 180-184, 1963

    公益社団法人 高分子学会

被引用文献 (1)*注記

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詳細情報 詳細情報について

  • CRID
    1390001206520858368
  • NII論文ID
    130004032371
  • DOI
    10.1295/koron1944.20.180
  • ISSN
    18848079
    00232556
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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