Polymerization of Unsaturated Dibasic Acid Derivatives
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- Yamada Masamori
- Department of Industrial Chemistry, Faculty of Engineering, Fukui University
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- Takase Iwao
- Department of Industrial Chemistry, Faculty of Engineering, Fukui University
Bibliographic Information
- Other Title
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- 不飽和二塩基酸誘導体の重合に関する研究
- III. Syntheses and Polymerization of Alkyl Vinyl Maleates and Fumarates
- 第3報マレイン酸ならびにフマル酸のアルキルビニルエステルの合成, 重合について
Abstract
Ethyl-, n-propyl-, i-propyl and n-butyl vinyl maleates and fumarates were synthesised bythe vinyl interchange reaction of vinyl acetate with mono alky maleates, and the physicalproperties of these compounds were determined.<BR>With radical initiator, the highest rate of polymerization was obtained with the i-propylester.<BR>Percent cyclization of the polymerization products was measured by infrared spectroscopy.<BR>The poly maleates showed high 4-membered ring contents and lower 5-membered ring contents.In poly fumarates only a small amount of 5-membered ring was found to be formed.<BR>The observed difference in cyclization behavior in the two series of polymer was discussed.
Journal
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- Kobunshi Kagaku
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Kobunshi Kagaku 20 (215), 180-184, 1963
The Society of Polymer Science, Japan
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Details 詳細情報について
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- CRID
- 1390001206520858368
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- NII Article ID
- 130004032371
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- ISSN
- 18848079
- 00232556
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- Text Lang
- ja
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed