書誌事項
- タイトル別名
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- Polymerizations of Unsaturated Dibasic Acid Derivatives
- II. Syntheses and Polymerizations of Methylvinylmaleate and Fumarate
- 第2報 マレイン酸ならびにフマル酸のメチルビニルエステルの合成, 重合について
抄録
Methylvinylmaleate and fumarate were synthesized by Vinyl Interchange Reaction of vinylacetate with monomethylmaleate or fumarate and their physical properties were determined.<BR>The cyclization polymerizations of above monomers with radical initiator were studied and the initial rate of polymerization of fumarate was about thirty times as large as that of maleate.<BR>Residual double bond in polymers and infrared spectra of polymers indicated theformation of 5-membered lactone ring in both polymers and another 4-membered lactone ringin polymaleate. The difference of percent cyclization between two polymers was discussed.
収録刊行物
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- 高分子化學
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高分子化學 19 (201), 11-15, 1962
公益社団法人 高分子学会
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詳細情報 詳細情報について
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- CRID
- 1390001206520859392
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- NII論文ID
- 130004032289
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- ISSN
- 18848079
- 00232556
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可