書誌事項
- タイトル別名
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- Photocontrol of Polypeptide Conformation
- ポリペプチド コンホメーション ノ ヒカリ セイギョ
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抄録
Five copolypeptide series containing azobenzene groups in their side-chains were prepared in order toinvestigate the effect. of photoisomerization of the side-chain azobenzenc groups on the polypeptide conformations. It was found by circular dichroism (CD) measurements that conformational changes such as lefthanded (LH) helix→right-handed (RH) helix, LH helix→random coil and random coil→RH helix are inducedby photoirradiation. It was also found that a copolymer which undergoes a solvent-induced RH helix→LHhelix→random coil transition exhibits remarkable dependency of its photoresponsive behavior on the solventcomposition. There seemed no general relation between the main-chain helical sense and, the sign of theside-chain CD band for the five copolymer series.
収録刊行物
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- 高分子論文集
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高分子論文集 37 (4), 281-286, 1980
公益社団法人 高分子学会
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詳細情報 詳細情報について
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- CRID
- 1390001206521336576
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- NII論文ID
- 130004033906
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- NII書誌ID
- AN00085011
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- ISSN
- 18815685
- 03862186
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- NDL書誌ID
- 2179254
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可