Synthesis and polymerization of 2-amino-4-(p-alkyloxyanilino)-6-isopropenyl-1,3,5-triazines.

DOI Web Site 3 Citations
  • KUNISADA Hideo
    Department of Meterial Science and Engineering, Nagoya Institute of Technology
  • YUKI Yasuo
    Department of Meterial Science and Engineering, Nagoya Institute of Technology
  • MATUSITA Yosihumi
    Department of Meterial Science and Engineering, Nagoya Institute of Technology
  • INUZUKA Minoru
    Department of Meterial Science and Engineering, Nagoya Institute of Technology
  • YAMAZAKI Masahiro
    Department of Meterial Science and Engineering, Nagoya Institute of Technology
  • YOSIDA Takasi
    Department of Meterial Science and Engineering, Nagoya Institute of Technology

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Other Title
  • ２‐アミノ‐４‐（ｐ‐アルキルオキシアニリノ）‐６‐イソプロペニル‐１，３，５‐トリアジンの合成と重合
  • 2 アミノ 4 p アルキルオキシアニリノ 6 イソプロペニル 1 3 5 ト

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Abstract

2-Amino-4- (p-alkyloxyanilino) -6-isopropenyl-1, 3, 5-triazines (pCnIT, where “n” means the number of alkyl carbon atoms) were prepared by the reaction of p-alkyloxyphenylbiguanide with methacryloyl chloride for pC4IT, pC6IT, and pC8IT or by the reaction of 2-amino-4- (p-hydroxyanilino) -6-isopropenyl-1, 3, 5-triazine with alkyl bromides for pC10IT-pC18IT. New comb-like polymers were prepared by the homopolymerizations and copolymerizations of pCnIT with styrene, methyl methacrylate, and methyl acrylate (M1) in dimethyl sulfoxide using azobisisobutyronitrile as the initiator. The copolymerization parameters (r1, r2, Q, and e values) were determined. Glass transition temperatures of poly-pC6IT-poly-pC18IT were 192-196°C. The long alkyl side chains of poly-pC12IT-poly-pC18IT can crystallize at around 0°C.

Journal

  • KOBUNSHI RONBUNSHU

    KOBUNSHI RONBUNSHU 47 (1), 33-40, 1990

    The Society of Polymer Science, Japan

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