Diffusion of Li+ Ions into Multilayers of Aluminum Stearate Deposited on Polymeric Solid Electrolytes.
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- ORIHARA Katsuo
- Department of Polymer Materials Engineering Faculty of Engineering Yamagata University
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- OSADA Tsutomu
- Department of Polymer Materials Engineering Faculty of Engineering Yamagata University
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- SASADA Hiroyuki
- Department of Polymer Materials Engineering Faculty of Engineering Yamagata University
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- TAKEBAYASHI Hiroyuki
- Department of Polymer Materials Engineering Faculty of Engineering Yamagata University
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- MURAYAMA Tsutomu
- Department of Polymer Materials Engineering Faculty of Engineering Yamagata University
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- NARISAWA Ikuo
- Department of Polymer Materials Engineering Faculty of Engineering Yamagata University
Bibliographic Information
- Other Title
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- 高分子固体電界質上に蒸着したステアリン酸アルミニウム薄膜へのリチウムイオンの拡散
Abstract
The diffusion of Li+ ions from a polymeric Solid electrolyte (PSE) into multilaycrs of aluminum Stearate dimer (SA-Al (di)) was investigated at a D. C. voltage of 10mV. The multilayer was deposited on the PSE in vacuum at 2.0 ×10-5 Torr. The PSE consists of LiClO4, Poly (ethylene oxide) (PEO) and poly (vinyl acetate) (PVAc). DiffuSion of dissociated Li+ in PSE substrate into the multilayers was observed. The diffusion was larger when the voltage was Supphed at 4°C than at-10°C or 40°C. The Li+seemes to bind again with ClO-4 or to coordinate to the oxygen atoms of the SA-AR (di) in the multilayers. The above results can be applied for the fabrication of high quality organicinorganic layered superlattices by means of doping inorganic materials into the organic multilayers.
Journal
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- KOBUNSHI RONBUNSHU
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KOBUNSHI RONBUNSHU 51 (12), 778-782, 1994
The Society of Polymer Science, Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390001206521858816
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- NII Article ID
- 130004034975
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- ISSN
- 18815685
- 03862186
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- Text Lang
- ja
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed