Stabilization of poly(vinyl chloride). VII. Synergetic effects of sulfur-containing compounds with zinc stearate/calcium stearate synergetic soap on the stabilization of poly(vinyl chloride).
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- IIDA Takeo
- Department of Applied Chemistry, Osaka Institute of Technology
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- HAYASHI Satsuki
- Department of Applied Chemistry, Osaka Institute of Technology
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- GOTO Kunio
- Department of Applied Chemistry, Osaka Institute of Technology
Bibliographic Information
- Other Title
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- ポリ塩化ビニルの安定化に関する研究 VII ポリ塩化ビニルの熱安定化に対する含硫黄化合物とステアリン酸亜鉛/ステアリン酸カルシウム複合系金属石けんとの相乗効果
- ポリ エンカ ビニル ノ ネツ アンテイカ ニ タイスル ガン イオウ カゴウ
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Description
Effects of various sulfur-containing compounds on the zinc stearate/calcium stearate soap induced thermal stabilization of poly (vinyl chloride) (PVC) were investigated by colorimetry. t-Nonylmercaptane, dithioglycol, β-mercaptopropionic acid, and thiourea markedly enhanced thermal stabilization of PVC containing zinc stearate/calcium stearate soap, while octylmercaptane, di (n-octyl) sulfide, a-mercaptopropionic acid, and 2-ethylhexylmercaptoacetate did not exhibit measurable enhancements in the stability. IR spectroscopy and X-ray photoelectron spectroscopy on the sulfur-containing compound-metal soap-PVC mixtures indicated that the sulfur-containing compounds, which were effective as additives, formed complexes with zinc chloride deriving from the metal soap. Such complexes were not observed for the sulfur-containing compounds which were less effective. The synergetic effect between the sulfur-containing compounds and the metal soap was ascribed to mask the excessive zinc chloride by the sulfur-containing compounds.
Journal
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- KOBUNSHI RONBUNSHU
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KOBUNSHI RONBUNSHU 43 (6), 319-324, 1986
The Society of Polymer Science, Japan
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Details 詳細情報について
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- CRID
- 1390001206521956608
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- NII Article ID
- 130004034378
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- NII Book ID
- AN00085011
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- ISSN
- 18815685
- 03862186
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- NDL BIB ID
- 3095110
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed