ポリトリメチレンテレフタレート繊維のアニーリングによる構造変化

書誌事項

タイトル別名
  • Annealing Effect on Structure of Poly(trimethylene terephthalate) Undrawn Fibers

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説明

The undrawn monofilament of poly (trimethylene terephthalate) (PTT) was obtained by melt-spinning. After being treated at 40°C, it was analyzed by the measurements of differential scanning calorimetry (DSC), dynamic viscoelasticity (DMA), wide-angle X-ray diffraction (WAXD) and attenuated total reflection infrared spectra (ATR FT-IR). The glass transition temperature of PTT fiber after annealing for more than 96 hours was 20°C higher than that before annealing as determined by the DSC and DMA measurements. The WAXD analysis showed very weak diffraction peaks at 2θ=17° and 2θ=24° for the annealing time of more than 96 hours. The ATR FT-IR measurements made clear the conformational change of methylene chains of PTT glycol residue from random to gauche-gauche conformation.

収録刊行物

  • 高分子論文集

    高分子論文集 60 (11), 616-621, 2003

    公益社団法人 高分子学会

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詳細情報 詳細情報について

  • CRID
    1390001206522306816
  • NII論文ID
    130004035575
  • DOI
    10.1295/koron.60.616
  • ISSN
    18815685
    03862186
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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