Studies on synthesis and polymerization of unsaturated dibasic acid derivatives. XXIV. Radical terpolymerization of .ALPHA.-methylstyrene and acrylonitrile with N-phenyl- and N-p-chlorophenylmaleimides and thermal properties of the terpolymers.

DOI 2 Citations
  • TAKASE Iwao
    Department of Industrial Chemistry, Faculty of Engineering, Fukui University
  • MITAMURA Hiroshi
    Department of Industrial Chemistry, Faculty of Engineering, Fukui University
  • HISAMATSU Megumi
    Department of Industrial Chemistry, Faculty of Engineering, Fukui University
  • AIDA Hiroshi
    Department of Industrial Chemistry, Faculty of Engineering, Fukui University
  • KOHKAME Hisashi
    Hitachi Chemical Co., Ltd.

Bibliographic Information

Other Title
  • 不飽和二塩基酸誘導体の合成と重合に関する研究　第２４報　α‐メチルスチレン，アクリロニトリルとＮ‐フェニルマレイミド，及びＮ‐ｐ‐クロロフェニルマレイミド三元共重合体の合成と熱的性質

Abstract

Terpolymerizations of α-methylstyrene (MS) and acrylonitrile (AN) with N-phenylmaleimide (PMI) or N-p- chlorophenyhnaleimide (CPMI) were carried out by dropping a solution of different amounts of PMI or CPMI in cyclohexanone into the MS-AN copolymerization system in the presence of radical initiator at 80°C. Five terpolymers containing about 3 to 17 mol% of PMI or CPMI units were obtained. The thermal behavior of the terpolymers was examined by TG and DSC measurements. In both series of terpolymers, the glass transition and initial thermal decomposition temperatures and softening point increased markedly with increasing PMI or CPMI composition in the terpolymers.

Journal

  • KOBUNSHI RONBUNSHU

    KOBUNSHI RONBUNSHU 47 (8), 683-689, 1990

    The Society of Polymer Science, Japan

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Keywords

Details 詳細情報について

  • CRID
    1390001206522501504
  • NII Article ID
    130004034679
  • DOI
    10.1295/koron.47.683
  • ISSN
    18815685
    03862186
    http://id.crossref.org/issn/03862186
  • Text Lang
    ja
  • Data Source
    • JaLC
    • Crossref
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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