書誌事項
- タイトル別名
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- Recent Developments in Transition Metal-Catalyzed Polymerization I. Recent Development of Transition Metal-Catalyzed Living Radical Polymerization-Design and Development of the Metal Complexes.
- センイ キンゾク ショクバイ ニ ヨル リビング ラジカル ジュウゴウ ノ シン テンカイ キンゾク ショクバイ ノ セッケイ ト セイミツ ジュウゴウケイ ノ カイハツ
- Design and Development of the Metal Complexes
- 金属触媒の設計と精密重合系の開発
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This article covers recent developments in transition metal-catalyzed living radical polymerization, specifically focusing on the design of the metal complexes. The metal-catalyzed systems, each consisting of an organic halide (initiator) and a metal complex (catalyst), polymerize a wide variety of vinyl monomers to give polymers with controlled molecular weights, their narrow distributions, and well-defined main-chain and/or end-group structures. The polymerization proceeds via radical species generated by the reversible and homolytic activation of terminal dormant carbon-halogen bonds by transition metal complexes. Careful selections of the central metal and the ligands are necessary depending on the types of monomers. In addition to the scope and the design of the metal catalysts, the article also outlines the polymerization mechanism and living radical polymerization in aqueous media.
収録刊行物
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- 高分子論文集
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高分子論文集 59 (4), 199-211, 2002
公益社団法人 高分子学会
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詳細情報 詳細情報について
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- CRID
- 1390001206523189504
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- NII論文ID
- 10008223906
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- NII書誌ID
- AN00085011
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- ISSN
- 18815685
- 03862186
- http://id.crossref.org/issn/03862186
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- NDL書誌ID
- 6154290
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可