液晶ポリエーテルエステルの熱的性質と機械的性質

書誌事項

タイトル別名
  • Thermal and mechanical properties of thermotropic polyether-esters.
  • エキショウ ポリエーテルエステル ノ ネツテキ セイシツ ト キカイテキ セイ

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説明

A number of thermotropic polyarylate have been prepared from substituted hydroquinone, 1, 2-bis (phenoxy) ethane-4, 4′-dicarboxylic acid and 1, 2-bis (2-chlorophenoxy) ethane-4, 4′-dicarboxylic acid. A fiber from methyl-hydroquinone 1, 2-bis (2-chlorophenoxy) ethane-4, 4′-dicarboxylate showed a Young's modulus of 72GPa (0.11mmφ), which would be the highest value ever reported for homopolyarylates. 2, 7-Dihydroxynaphthalene 1, 2-bis (phenoxy) ethane-4, 4′-dicarboxylate and 1, 2-bis (2-chlorophenoxy) ethane-4, 4′-dicarboxylate have also been prepared. The former showed a liquid crystallinity, in spite of its asymmetrical structure, while the latter showed no liquid crystallinity.

収録刊行物

  • 高分子論文集

    高分子論文集 43 (5), 261-267, 1986

    公益社団法人 高分子学会

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