精密重合・精密合成高分子Ｉ　　テトラシアノエチレンと種々のビニルエーテルとのシクロブタン付加物の合成とその擬リビングカチオン開環重合

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タイトル別名
  • Precision Polymerization and Polymers I. Synthesis and Pseudo-Living Cationic Ring-Opening Polymerization of Cyclobutane Adducts of Tetracyanoethylene and Various Vinyl Ethers.
  • テトラシアノエチレン ト シュジュ ノ ビニルエーテル ト ノ シクロブタン

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説明

A variety of cyclobutane adducts of tetracyanoethylene (TCNE) and various vinyl ethers are prepared and their pseudo-living cationic ring-opening polymerization is studied. The cyclobutane adducts of TCNE and n-butyl vinyl ether or methyl vinyl ether underwent pseudo-living cationic ring-opening polymerization with ethyl vinyl ether-acetic acid adduct/ZnI2 in nitromethane at ambient temperature, similar to the polymerization behavior of the cyclobutane adduct of TCNE and ethyl vinyl ether with the same catalyst as reported previously. In the polymerizations of the cyclobutane adducts of TCNE and vinyl ethers with functional side chains, the cyclobutane bearing the 2-methoxyethoxy group underwent pseudo-living polymerization with the same catalyst.

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  • 高分子論文集

    高分子論文集 54 (10), 716-722, 1997

    公益社団法人 高分子学会

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