クワドリシクレンの異性化に用いる高分子触媒の合成と性質

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タイトル別名
  • Synthesis and property of polymer-anchored cobalt catalysts for the isomerization of quadricyclene.
  • クワドリシクレン ノ イセイカ ニ モチイル コウブンシ ショクバイ ノ ゴウ

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抄録

In order to realize the photochemical conversion and storage system of solar energy based on the reversible valence isomerization of norbornadiene to quadricyclene, polymer-anchored cobalt catalysts were synthesized and their properties were examined for the isomerization of quadricyclene to norbornadiene. Polymeranchored cobalt catalysts were prepared by graft-copolymerizing chloromethylstyrene onto porous polyethylene, cellulose acetate and glass fibers and then making ester linkages between the chloromethyl groups and carboxyl groups of cobalt porphine. The resulting catalysts were highly active, easily handled and very stable in the isomerization of quadricyclene to norbornadiene compared with monomeric cobalt porphines.

収録刊行物

  • 高分子論文集

    高分子論文集 44 (6), 437-444, 1987

    公益社団法人 高分子学会

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