NMR Spectra Analysis of Poly (1,3-cyclohexadiene)

DOI
  • NATORI Itaru
    Electronic Materials & Devices Laboratory, Corporate R & D Administration, Asahi Kasei Corporation
  • KAZUNORI Miyuki
    Analytical & Computational Science Department, Central Technology Laboratory, Corporate R & D Administration, Asahi Kasei Corporation
  • YAMAGISHI Hideyuki
    Residential Systems & Material Laboratory, Corporate R & D Administration, Asahi Kasei Corporation

Bibliographic Information

Other Title
  • ポリ（１，３－シクロヘキサジエン）のＮＭＲスペクトルの解析

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Description

The NMR spectra of poly (1, 3-cyclohexadiene) (PCHD) were studied. PCHD was synthesized by living anionic polymerization of 1, 3-cyclohexadiene (1, 3-CHD) with the n-butyllithium (n-BuLi) /N, N, N′, N′-tetramethylethylenediamine (TMEDA) system as an initiator. PCHD has a structure consisting of a main chain formed by1, 2-addition (1, 2-unit) and 1, 4-addition (1, 4-unit). The complicated 1H and 13C NMR spectra of poly (1, 3-cyclohexadiene) (PCHD) were observed. The spectral assignment of 1H NMR spectrum of PCHD with the 1, 2-units and 1, 4-units was determined by two dimensional (2D) and Distortionless Enhancement by Polarization Transfer (DEPT) NMR spectroscopy techniques.

Journal

  • KOBUNSHI RONBUNSHU

    KOBUNSHI RONBUNSHU 61 (3), 197-199, 2004

    The Society of Polymer Science, Japan

Keywords

Details 詳細情報について

  • CRID
    1390001206524097664
  • NII Article ID
    130004035666
  • DOI
    10.1295/koron.61.197
  • ISSN
    18815685
    03862186
  • Text Lang
    ja
  • Data Source
    • JaLC
    • Crossref
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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