Polymer Synthesis Exploiting Nitrile <i>N</i>-Oxide

DOI Web Site Web Site 9 Citations 205 References Open Access
  • KOYAMA Yasuhito
    Department of Organic and Polymeric Materials, Tokyo Institute of Technology
  • TAKATA Toshikazu
    Department of Organic and Polymeric Materials, Tokyo Institute of Technology

Bibliographic Information

Other Title
  • ニトリルオキシドを用いる高分子合成
  • ニトリルオキシド オ モチイル コウブンシ ゴウセイ

Search this article

Description

Highly sophisticated supramolecular and macromolecular multi-component architectures strongly require viable means of powerful, versatile, and reliable synthetic routes. For this purpose, nitrile N-oxide is potentially useful as a ‘molecular glue’ between functional components because nitrile N-oxide allows catalyst-free reactions with various unsaturated bonds, along with a rigid C-C bond formation. However, there are only a few reports concerning applications of nitrile N-oxides toward a chemical modification and a chemical ligation, probably due to the extreme reactivity of nitrile N-oxides leading to spontaneous dimerization to give a furoxan. This paper summarizes the reports of polymer synthesis exploiting nitrile N-oxides. Through the historical survey, the efficiency and application of our recently developed method of polymer synthesis, based on the kinetic stabilization of nitrile N-oxides, are discussed in detail.<br>

Journal

  • KOBUNSHI RONBUNSHU

    KOBUNSHI RONBUNSHU 68 (4), 147-159, 2011

    The Society of Polymer Science, Japan

Citations (9)*help

See more

References(205)*help

See more

Related Projects

See more

Keywords

Details 詳細情報について

Report a problem

Back to top