Analysis of Sulfidic Linkages in Solvent-Extracted Sulfur Cross-Linked Isoprene Rubber
-
- YASUDA Yoritaka
- Graduate School of Science and Technology, Kyoto Institute of Technology
-
- TOHSAN Atitaya
- Graduate School of Science and Technology, Kyoto Institute of Technology
-
- LIMPHIRAT Wanwisa
- Synchrotron Light Research Institute
-
- IKEDA Yuko
- Graduate School of Science and Technology, Kyoto Institute of Technology
Bibliographic Information
- Other Title
-
- 溶媒抽出した硫黄架橋イソプレンゴムのスルフィド構造解析
- ヨウバイ チュウシュツ シタ イオウ カケハシ イソプレンゴム ノ スルフィド コウゾウ カイセキ
Search this article
Description
For the first time, sulfur K-edge X-ray absorption near-edge structure (S K-edge XANES) measurement was conducted at room temperature to evaluate a kind of the sulfidic linkage in solvent-extracted sulfur cross-linked isoprene rubbers. The vulcanizates were prepared by heat-pressing of the rubber compounds containing zinc oxide, stearic acid, N-cyclohexyl-2-benzothiazole sulfonamide and sulfur. The sulfidic linkage varied from a polysulfide type to a disulfide type with increasing of the torque during curing. A monosulfide type was also suggested to be generated from the disulfidic linkage. The S K-edge XANES measurement will be of use for evaluating a characteristic of the sulfidic linkages in the sulfur cross-linked rubber by combining the solvent extraction technique.
Journal
-
- KOBUNSHI RONBUNSHU
-
KOBUNSHI RONBUNSHU 72 (1), 16-21, 2015
The Society of Polymer Science, Japan
- Tweet
Details 詳細情報について
-
- CRID
- 1390001206526007680
-
- NII Article ID
- 130004793171
-
- NII Book ID
- AN00085011
-
- ISSN
- 18815685
- 03862186
-
- NDL BIB ID
- 026056359
-
- Text Lang
- ja
-
- Data Source
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- Abstract License Flag
- Disallowed