機械的特性と防汚性に優れる含フッ素ポリマーコンポジット—耐久性と審美性を備えた人工歯の開発

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タイトル別名
  • Fluorinated Polymer/Silica Composites with Remarkable Mechanical and Antifouling Properties—Design for Artificial Teeth with Improved Durability and Esthetics
  • 機械的特性と防汚性に優れる含フッ素ポリマーコンポジット : 耐久性と審美性を備えた人工歯の開発
  • キカイテキ トクセイ ト ボウオセイ ニ スグレル ガン フッソ ポリマーコンポジット : タイキュウセイ ト シンビセイ オ ソナエタ ジンコウバ ノ カイハツ
  • Fluorinated Polymer/Silica Composites with Remarkable Mechanical and Antifouling Properties^|^mdash;Design for Artificial Teeth with Improved Durability and Esthetics

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Two different types of fluorinated monomers were added to a conventional formulation for dental restorative material comprising a hydrocarbon-based methacrylic monomer and inorganic particulate fillers to afford fluorinated composites having sufficient strength and inertness. Fluorinated bisphenol-A dimethacrylate with ethylene glycols as the spacer between the core and methacryloyl groups, showed enough hydrophobicity and good compatibility with other components such as polyfluoroalkyl methacrylate, urethane methacrylate and silica particles, giving notable flexural strength, hardness, and anti-staining property to the composite. Without deteriorating the mechanical and anti-staining properties, the polyfluoroalkyl methacrylate compensated a high viscosity and a large refractive index of the aromatic fluoromonomer which reduced the amount of fillers to be loaded and the transparency of the composite. The fluorinated composite with fairly good mechanical properties, clarity, and antifouling character was found as the suitable material for artificial teeth with improved durability and esthetics.

収録刊行物

  • 高分子論文集

    高分子論文集 70 (4), 166-174, 2013

    公益社団法人 高分子学会

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