書誌事項
- タイトル別名
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- Influences of the Residual Peroxide on Degradation of Crosslinked EPDM
- カサンカブツ カキョウ エチレンプロピレンゴム ニ オケル ザンソン カサンカブツ ガ レッカ ニ オヨボス エイキョウ ノ ケントウ
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説明
The influences of residual peroxide on degradation and the detection methods for under-crosslinking were investigated.<br>The under-crosslinking of peroxide-crosslinked EPDM can be detected by differential scanning calorimetry (DSC) measurement of heat of residual crosslinking reaction, which was found to correlate with the amount of remaining dicumyl peroxide (DCP) and triallyl isocyanurate, without determination of their amounts. For the DCP-crosslinked EPDM in under-crosslinking state, it was considered that softening degradation occurs more remarkably than hardening degradation as long as the crosslinking agent remains. By surface analysis of aged DCP-crosslinked EPDM with FT-IR, it turned out that oxidative degradation of the EPDM in under-crosslinking state occurs faster than the EPDM without crosslinking agent remaining.
収録刊行物
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- 日本ゴム協会誌
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日本ゴム協会誌 80 (5), 165-171, 2007
一般社団法人 日本ゴム協会
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詳細情報 詳細情報について
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- CRID
- 1390001206561245440
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- NII論文ID
- 10018616635
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- NII書誌ID
- AN00189720
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- COI
- 1:CAS:528:DC%2BD2sXnvVegtb4%3D
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- ISSN
- 18840442
- 0029022X
- http://id.crossref.org/issn/0029022X
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- NDL書誌ID
- 8820555
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDLサーチ
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可
