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- 井上 隆
- 山形大学工学部機能高分子工学科
書誌事項
- タイトル別名
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- Polymer Blends: Principles and Applications: Part 1. Polymer-Polymer Miscibility and Applications of Miscible Blends
- トクロン コウザ ポリマー ブレンド ノ キソ ト オウヨウ 1 ソウヨウセイ ト オウヨウ
- Part 1. Polymer-Polymer Miscibility and Applications of Miscible Blends
- 1. 相溶性と応用
この論文をさがす
抄録
Thermodynamic discussion on the miscibility between dissimilar polymers leads to: (i) the contribution of combinatorial entropy of mixing to the miscibility is negligibly small and (ii) the miscibility is mostly caused by the hydrogen bonding-type intermolecular specific interactions and the repulsive intramolecular interactions in random copolymers. By analyzing the fee energy curve, the free energy of mixing as a function of composition, phase diagrams are described in terms of the binodal curve and the spinodal curve. Criterions of polymer-polymer miscibility are deduced in the framework of such thermodynamic discussion.<br>The polymer-polymer miscibility is applied: (i) to improve melt-processability (PPE/PS), (ii) to improve ozone resistance (NBR/PVC), (iii) to reduce optical anisotropy (to provide zero-birefringence plastics), (iv) to improve heat resistance (PEEK/PET), and (v) to make materials flexible (PVC/EVA).
収録刊行物
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- 日本ゴム協会誌
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日本ゴム協会誌 78 (3), 122-127, 2005
一般社団法人 日本ゴム協会
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詳細情報 詳細情報について
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- CRID
- 1390001206561296768
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- NII論文ID
- 10013818683
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- NII書誌ID
- AN00269207
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- ISSN
- 18840442
- 0029022X
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- NDL書誌ID
- 7279273
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可