書誌事項
- タイトル別名
-
- STUDIES OF ANTIOXIDANTS AND ANTIOZONANTS. (3)
- ホウコウゾク アミン カゴウブツ ノ サンカ デンイ オヨビ シガイ キュウシュウ スペクトル ニ ツイテ
- OXIDATION POTENTIALS AND ULTRAVIOLET ABSORPTION OF AROMATIC AMINES
この論文をさがす
抄録
The oxidation potentials of anilin, diphenylamine, p-phenylenediamine, and N-phenyl-p-phenyleenedia-mine derivatives were measured by using polarography under the same condition, and the highest occupied energy levels of these chemicals were caluculated by means of simple L.C.A.O-M.O. method.<br>The oxidation potentials were found to relate linearly to the levels, and the following equation was obtained;<br>Vo=2.3λ-0.95<br>where Vo was the potentials (volt).<br>Now, the energy from the lowest vacant level to the highest occupied level of these chemicals related linearly to the frequencies calculated from ultraviolet absorption. From the results, the reasonance integral β was found to be about 52kcal/mol, when α+2β was adopted as a coulomb integral of nitrogen.<br>From these results, the reaction energy for the reaction between the amine derivatives and ozone was assumed to be lower than 6kcal/mol.
収録刊行物
-
- 日本ゴム協会誌
-
日本ゴム協会誌 36 (5), 449-455, 1963
一般社団法人 日本ゴム協会
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1390001206562821120
-
- NII論文ID
- 130001269813
-
- NII書誌ID
- AN00269207
-
- ISSN
- 18840442
- 0029022X
-
- NDL書誌ID
- 9159909
-
- 本文言語コード
- ja
-
- データソース種別
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可