VULCANIZATION OF BUTADIENE-ACRYLONITRILE RUBBER USING A METAL CHLORIDE-HALOORGANIC COMPOUND SYSTEM

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Other Title
  • ルイス酸と有機ハロゲン化合物によるニトリルゴムの架橋
  • ルイスサン ト ユウキ ハロゲン カゴウブツ ニ ヨル ニトリルゴム ノ カキョウ
  • NON-SULFUR VULCANIZATION OF SYNTHETIC RUBBERS. II

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Abstract

An attempt was made to vulcanize butadiene-acrylonitrile rubber using a binary system of stannous chloride or zinc chloride and a halo-organic compound such as liquid chloroparaffin, polyvinyl chloride or polychloroprene.<br>These polyhalo-compounds exhibited powerful co-catalytic effects and the vulcanizates cured with these non-sulfur curing system showed higher values of abrasion resistance, modulus, hardness and tensile strength at break than those of vulcanizates cured with sulfur, but the former stocks had more tendency to premature vulcanization.<br>It is interesting from practical view point that liquid chloroparaffin and polyvinyl chloride may be used in rubber stocks as a reactive plasticizer and a reactive filler respectively.

Journal

  • NIPPON GOMU KYOKAISHI

    NIPPON GOMU KYOKAISHI 36 (7), 606-609, 1963

    THE SOCIRETY OF RUBBER SCIENCE AND TECHNOLOGYY, JAPAN

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