Effect of solvent polarity to molecular structure of alkanethiol monolayer on Ag

Bibliographic Information

Other Title
  • Ag上のアルカンチオール単分子膜の分子構造に及ぼす溶媒の極性の影響

Description

<p>Local structure of 11-Bromo-1-undecanethiol (BUDT) in organic self-assembled monolayer (SAM) chemisorbed on solvents / silver substrate interfaces (Ag/BUDT) were evaluated by using surface-enhanced Raman spectroscopy (SERS). The structure of the C-S moiety of the Ag/BUDT SAM was dependent on the polarity of the solvents. More BUDT formed the trans conformer in the C-S moiety in more polar solvents. On the other hand, in less polar solvents, the number of the trans conformer was decreased, therefore the composition of the SAM become more homegeneous.</p>

Journal

Details 詳細情報について

  • CRID
    1390001277376330240
  • NII Article ID
    130007737633
  • DOI
    10.14886/jvss.2019.0_2p47
  • ISSN
    24348589
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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