Photo- and electrocatalytic H<sub>2</sub> evolution with cobalt oxime complexes
-
- Willkomm Janina
- Christian Doppler Laboratory for Sustainable SynGas Chemistry, Department of Chemistry, University of Cambridge
-
- Reisner Erwin
- Christian Doppler Laboratory for Sustainable SynGas Chemistry, Department of Chemistry, University of Cambridge
抄録
<p>Converting sunlight into storable chemical energy carriers, such as dihydrogen (H2), through light-driven splitting of water is a widely studied approach to secure future energy supplies and sustainability. Molecular complexes based on inexpensive and earthabundant 3d transition metals have been extensively explored as catalysts for the reduction of water to H2. Among these, cobalt complexes with an oxime functionality (i.e., cobaloxime and cobalt diimine-dioxime) efficiently reduce protons in pure water with low to moderate overpotentials, and they have been shown to remain active under aerobic conditions. Based on their simple and straightforward synthesis in addition to their excellent electrochemical properties, they are often applied as the first-choice catalyst when testing new materials or introducing new concepts for H2 evolution. In this review, their basic electrochemical and electrocatalytic properties as well as mechanistic investigations will be summarized, followed by an overview of their application in photocatalysis. Finally, their integration with (nano)materials for (photo)electrocatalytic H2 evolution is presented and discussed.</p>
収録刊行物
-
- Bulletin of Japan Society of Coordination Chemistry
-
Bulletin of Japan Society of Coordination Chemistry 71 (0), 18-29, 2018-05-31
錯体化学会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390001288060928128
-
- NII論文ID
- 130007438840
-
- ISSN
- 18831737
- 18826954
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可