Pseudo Photorefractivity and Structural Correlation for Polyacrylate Containing Thioxanthene Moiety Doped with EO Active Chromophores

DOI Web Site 被引用文献1件 参考文献22件 オープンアクセス
  • Chiba Hibiki
    Graduate School of Bio-Applications and Systems Engineering, Tokyo University of Agriculture and Technology
  • Murata Tatsuya
    Graduate School of Bio-Applications and Systems Engineering, Tokyo University of Agriculture and Technology
  • Kanehashi Shinji
    Graduate School of Bio-Applications and Systems Engineering, Tokyo University of Agriculture and Technology
  • Ogino Kenji
    Graduate School of Bio-Applications and Systems Engineering, Tokyo University of Agriculture and Technology

この論文をさがす

説明

<p>Pseudo photorefractivity and structural correlation was investigated for the composites consisting of polyacrylate containing electron accepting thioxanthene (TH) moiety and electro-optical (EO) chromophore via a two beam coupling experiment. Tuning of electron accepting nature was achieved by the chemical modification of carbonyl group in 9-oxo-9 H- thioxanthene-10,10-dioxide unit. EO chromophores with various structural characteristics were examined. It is revealed that the stronger was the electron accepting nature,the lower was pseudo photorefractivity, and the composites with EO chromophore exhibiting photoisomerization showed the higher coupling gains. It is considered that excessive charge transfer interaction impedes the photoalignment followed by the migration of EO chromophore, and cis-trans photoisomerization is an essential step to create the refractive index grating phase-shifted with the interference pattern.</p>

収録刊行物

被引用文献 (1)*注記

もっと見る

参考文献 (22)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ