書誌事項
- タイトル別名
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- Development of Conducting Charge-Transfer Complexes Based on Cooperation of Hydrogen-Bond and Charge-Transfer Interactions
- スイソ ケツゴウ ト デンカ イドウ ソウゴ サヨウ ノ キョウソウ ニ モトズク ドウデンセイ デンカ イドウ サクタイ ノ カイハツ
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<p>Conducting charge-transfer complexes and salts have attracted much attention of organic chemists, physicists and materials scientists for 60 years, and is an active research area in the development of functional organic materials. We have been studying the hydrogen-bonded charge-transfer complexes where the cooperation of hydrogen-bond and charge-transfer interactions causes new functions and phenomena induced by the well-defined self-assembled networks and cooperative proton-electron transfer. This review deals with our recent studies on the designs and syntheses of hydrogen-bonded charge-transfer complexes based on the tetrathiafulvalene derivatives with hydrogen-bonding functional groups (nucleobases and imidazoles) and tetracyanoquinodimethane radical anion salts with protonated oligo (imidazole) cations. The investigations revealed that the self-assembling ability by hydrogen-bonds constructs various supramolecular architectures involving the conduction columns and further that the donor-acceptor hydrogen-bonds modulates the electronic structure producing highly conductive charge-transfer complexes.</p>
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 77 (4), 318-329, 2019-04-01
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390001288146471680
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- NII論文ID
- 130007625045
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 029671207
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 使用不可