Selective separation of biomass-derived sugars and aromatics with metal-organic framework NU-1000
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- Yabushita Mizuho
- Institute of Multidisciplinary Research for Advanced Materials, Tohoku University
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- Fukuoka Atsushi
- Institute for Catalysis, Hokkaido University
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- Farha Omar K.
- Department of Chemistry, Northwestern University
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- Katz Alexander
- Department of Chemical and Biomolecular Engineering, University of California, Berkeley
Bibliographic Information
- Other Title
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- 金属有機構造体NU-1000を用いたバイオマス由来糖化合物と芳香族化合物の選択吸着・分離
Abstract
<p>Metal-organic framework (MOF) NU-1000, which consists of pyrene linkers, has been demonstrated to selectively adsorb biomass-derived aromatic compounds including furanics and phenolics in an aqueous mixture, without causing detectable adsorption of sugars. This outstanding molecular recognition property of NU-1000 should be originated from small-sized pyrene linkers that are organized and isolated in the MOF structure by inorganic nodes; thus, the pyrene linker cannot interact with a sugar molecule via CH–π interaction, but instead forms π–π interaction with an aromatic molecule.</p>
Journal
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- Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute
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Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute 2019f (0), 15-, 2019
The Japan Petroleum Institute
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Details 詳細情報について
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- CRID
- 1390002184859906560
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- NII Article ID
- 130007778070
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- Text Lang
- ja
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- Data Source
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- JaLC
- CiNii Articles
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- Abstract License Flag
- Disallowed