Network Polymer Benzoxazines

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  • Takeshi Endo
    Molecular Engineering Institute, Kindai University
  • Atsushi Sudo
    Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University

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  • ネットワークポリマー ベンゾオキサジン類
  • ネットワークポリマー ベンゾオキサジン類 : 新しいベンゾオキサジン類の分子設計と重合プロセス
  • ネットワークポリマー ベンゾオキサジンルイ : アタラシイ ベンゾオキサジンルイ ノ ブンシ セッケイ ト ジュウゴウ プロセス
  • ─New Molecular Designs and Polymerization Processes of Benzoxazines─
  • ー ベンゾオキサジン類 ─新しいベンゾオキサジン類の分子設計と重合プロセス─

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Abstract

<p>1,3-Benzoxazines have attracted considerable attention as monomers for high performance networked polymers. Their facile syntheses with combining a wide range of phenols, amines, and formaldehyde derivatives have allowed the diverse designs of 1,3-benzoxazines. In addition, combinations of 1,3-benzoxazines with other conventional monomers and reactants have enabled the development of new polymerization processes of 1,3-benzoxazines. This review paper presents the stream of our investigations on the polymerization mechanisms of 1,3-benzoxazines that brought us to the development of 1) a series of highly reactive 1,3-benzoxazines based on neighboring group participation and introduction of thioether groups and 2) a couple of reactions of 1,3-benzoxazines such as the addition reaction with resorcinols and thiols that proceed efficiently without heating.</p>

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