Design and Synthesis of Responsive Functional Molecules Based on Metal Complexes and Their Dynamic Structural Conversions
-
- Akine Shigehisa
- Nano Life Science Institute / Graduate School of Natural Science and Technology, Kanazawa University
Bibliographic Information
- Other Title
-
- 錯体化学に基づく応答性機能分子の創製と動的構造変換
- Award Accounts 錯体化学に基づく応答性機能分子の創製と動的構造変換
- Award Accounts サクタイ カガク ニ モトズク オウトウセイ キノウ ブンシ ノ ソウセイ ト ドウテキ コウゾウ ヘンカン
Search this article
Abstract
<p> Metal complexes are generally dynamic due to the reversibility of formation/cleavage of the coordination bonds. Therefore, metal complexes could be used as platforms for switchable functional molecules with dynamic structural changes. In order to achieve structural conversions as intended, finely designed organic frameworks as well as metal centers with appropriate lability are necessary. For this purpose, the author has focused on macrocyclic, acyclic, and cage-like oligosalen structures, which can incorporate multiple metal centers at desired positions. In this review, various kinds of dynamic structural conversions, such as helicity inversion of helical complexes and open/close functions of molecular cage structures, which were developed by the author and coworkers, are described.</p>
Journal
-
- Bulletin of Japan Society of Coordination Chemistry
-
Bulletin of Japan Society of Coordination Chemistry 75 (0), 13-27, 2020-05-31
Japan Society of Coordination Chemistry