Determination of Asulam in Livestock Products by LC-MS/MS

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  • LC-MS/MSによる畜産物中のアシュラム分析法
  • LC-MS/MS ニ ヨル チクサンブツ チュウ ノ アシュラム ブンセキホウ

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Abstract

<p>An analytical method based on LC-MS/MS was developed for the determination of asulam in livestock products. Asulam in livestock products was extracted with acetone. The crude extracts were defatted by acetonitrile and n-hexane partitioning. Cleanup was carried out using a combination of ethylene diamine-N-propyl silylation silica gel (PSA) and octadecyl silylated silica gel (C18) mini columns with acidic condition. The sample solution was subjected to LC-MS/MS using an external solvent calibration curve. The average recovery (n=5) of Asulam from four types of livestock products (bovine muscle, bovine fat, bovine liver and milk) spike at the maximum residue limits (MRLs) or at a uniform limit of 0.01 mg/kg was 92.7–98.7%, with a relative standard deviation of 3.1–11.6%. The limit of quantitation of the developed method was calculated to be 0.01 mg/kg.</p>

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