Unstable intermediate of methanol synthesis by CO<sub>2</sub> hydrogenation on Cu(111) surface
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- Kojima Ryusei
- University of Tsukuba
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- Sawaki Yasutaka
- University of Tsukuba
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- Takeyasu Kotaro
- University of Tsukuba
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- Kondo Takahiro
- University of Tsukuba
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- Fujitani Tadahiro
- National Institute of Advanced Industrial Science and Technology
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- Nakamura Junji
- University of Tsukuba
Bibliographic Information
- Other Title
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- Cu(111)表面上でのCO<sub>2</sub>水素化によるメタノール合成の不安定中間体
Abstract
<p>In the methanol synthesis by CO2 hydrogenation on the Cu catalyst, in order to observe the hydrogenation process after formate(HCOO) and unstable intermediates, formate is adsorbed on the Cu(111) model surface and is hydrogenated by the atomic hydrogen at low temperature. Formate reversibly adopted bidentate and monodentate structures, and a chemical species considered to be dioxymethylene and formaldehyde were observed.</p>
Journal
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- Abstract book of Annual Meeting of the Japan Society of Vacuum and Surface Science
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Abstract book of Annual Meeting of the Japan Society of Vacuum and Surface Science 2021 (0), 3Ca09-, 2021
The Japan Society of Vacuum and Surface Science
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Details 詳細情報について
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- CRID
- 1390009018101021184
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- NII Article ID
- 130008134232
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- ISSN
- 24348589
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- Text Lang
- ja
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- Data Source
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- JaLC
- CiNii Articles
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- Abstract License Flag
- Disallowed