カルベニウム炭素を陽イオン，ジチオおよびジセレノカルボキシラートのカルコゲン原子を陰イオンとする分子内塩の化学<総説　レビュー>

DOI IR

Description

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The present article describes 1) development in new syntheses of the inner salts in　which the carbocation and the dithiocarboxylate carbons are directly connected, 2) anomalous reactivities of the above inner salts toward nucleophiles, 3) synthesis and reactivities of the inner salts where the carbocation and the dithiocarboxylate carbons are insulated by an sp3 carbon atom, 4) synthesis and reactivities of the diselenocarboxylate and elenothiocarboxylate inner salts, and 5) molecular structures of the inner salts (X-ray crystallographic nalyses).

Journal

  • CACS FORUM

    CACS FORUM 20 7-20, 2000

    埼玉大学分析センター

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