Synthesis and Properties of Poly ((Perfluoroalkyl) sulfonyl) amides and Methanide Ions as New Types of Anionic Phase-Transfer Catalysts in Azo Coupling Reactions
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- 小林 宏
- 九州大学機能物質科学研究所
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- Meyer Zu Duttingdorf Hans-Dieter
- (Present Address)Fakultat fur Chemie, Universitat Bielefeld
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- 聶 進
- 華中理工大学化学系
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- 園田 高明
- 九州大学機能物質科学研究所
書誌事項
- タイトル別名
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- Synthesis and Properties of Poly Perflu
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説明
A series of lithium salts of bis ((perfluoroalkyl) sulfonyl) amides (1) with different chain lengths of perfluoroalkyl group and tris ((trifluoromethyl) sulfonyl) methanide (TTM) were prepared. The influence of the polyfluoroalkyl chain length of the imide ions on the solubility of their benzyltrimethylammonium salts in water and the partition coefficients (α) in dichloromethane/water system were discussed with respect to the applicability of these anions to new types of anionic phase-transfer catalysts. The catalytic activities of these anions were compared with TFPB anions in the azo coupling reactions of p-nitrobenzenediazonium ions with N-ethylcarbazole in dichloromethane/water and dichloromethane/solid two-phase systems.
収録刊行物
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- 九州大学機能物質科学研究所報告
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九州大学機能物質科学研究所報告 8 (2), 231-243, 1995-03-01
九州大学機能物質科学研究所
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詳細情報 詳細情報について
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- CRID
- 1390009224835553152
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- NII論文ID
- 110006177452
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- NII書誌ID
- AN10060378
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- ISSN
- 09143793
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- DOI
- 10.15017/6661
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- HANDLE
- 2324/6661
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- NDL書誌ID
- 3600428
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- IRDB
- NDL
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用可