Smart Design of Organometallic Catalysts to Induce Innovative Material Transformations
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- MATSUMOTO Takahiro
- Dept. of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University Precursory Research for Embryonic Science and Technology (PRESTO), Japan Science and Technology Agency (JST)
Bibliographic Information
- Other Title
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- ターゲット反応を誘起する錯体化学的スマートデザイン
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Description
<p>Coordination chemistry has established the principle of “organometallic smart design: metal × ligand” for metal complexes with specific properties and functions based on empirical rules and quantum chemistry considerations. Numerous metal complexes have subsequently been synthesized to catalyze required chemical reactions. This review describes several representative studies, especially concerning the reactions of designed metal complexes with dioxygen, dihydrogen, and methane gases. Copper-mediated dioxygen activation and nickel–iron-mediated dihydrogen activation were inspired by the enzymatic activities of tyrosinase and nickel–iron hydrogenase. Hydroxylation of arene ring, epoxidation of styrene, and oxidation of carbon–hydrogen bonds of hydrocarbons have been achieved using a dinuclear copper peroxide complex derived from dioxygen modelled on tyrosinase. Biomimetic dihydrogen oxidation and dioxygen reduction have been promoted by nickel–iron and nickel–ruthenium complexes in organic solvent and water, based on the oxygen-tolerant nickel–iron hydrogenase. The transformation of methane to methanol and formaldehyde using dioxygen as an oxidant has been achieved by input of light energy into a designed diruthenium dioxide complex.</p>
Journal
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- Journal of the Japan Petroleum Institute
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Journal of the Japan Petroleum Institute 65 (4), 134-139, 2022-07-01
The Japan Petroleum Institute
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Details 詳細情報について
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- CRID
- 1390011108717947648
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- NII Book ID
- AA11590615
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- ISSN
- 1349273X
- 13468804
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- NDL BIB ID
- 032268192
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL Search
- Crossref
- OpenAIRE
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- Abstract License Flag
- Disallowed