Innovation in Coordination Structural Chemistry by Synchrotron Radiation Science and Maximum Entropy Method
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- Takata Masaki
- International Center for Synchrotron Radiation Innovation Smart
Bibliographic Information
- Other Title
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- X 線は電子のプローブである- 放射光科学と最大エントロピー法による錯体構造化学の革新-
Abstract
<p>Since 2002, the structural science via Maximum Entropy Method based on synchrotron radiation(SR) diffraction data has driven an innovation of structural chemistry in Coordination Chemistry at SPring-8. The first successful contribution of the MEM Structural Science was a discovery of the peculiar structure of absorbed gas molecules in the nanopore of coordination polymer. The revealed one-dimensional array structure of absorbed gas molecules with no charge transfer made chemists recognize the power of Synchrotron Radiation as a probe of electrons in materials. The development of the MEM/Rietveld Method is described in terms of absorbed molecular site prediction as well as finding charge transfer among host-guest molecules. The expected role of the Next Generation Synchrotron Radiation facility under construction at Tohoku University Campus is also noted.</p>
Journal
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- Bulletin of Japan Society of Coordination Chemistry
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Bulletin of Japan Society of Coordination Chemistry 79 (0), 100-105, 2022-06-06
Japan Society of Coordination Chemistry
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Keywords
Details 詳細情報について
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- CRID
- 1390011231115389696
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- ISSN
- 18831737
- 18826954
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- Text Lang
- ja
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- Data Source
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- JaLC
- Crossref
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- Abstract License Flag
- Disallowed