ギ酸塩を原料とする二酸化炭素ラジカルアニオンの発生と光反応への利用

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  • Generation of Carbon Dioxide Radical Anion from Formate Salts and its Use in Photochemical Reactions

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<p>Carbon dioxide radical anion (CO2·−) is a reactive intermediate that can act as a powerful single electron reductant as well as a nucleophilic C1 radical source. However, its utility has not been well explored due to the fact that direct reductive approaches to access CO2·− from thermodynamically stable CO2 require deeply reducing conditions. This review focuses on a recently developed approach for the generation of CO2·− via hydrogen-atom transfer under practical and mild conditions, which has enabled a variety of transformations that are difficult to achieve by conventional methods.</p>

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