ニッケル触媒作用による二酸化炭素の挿入機構を利用した選択的炭素-炭素結合形成

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  • Highly Regio- and Stereoselective C-C Bond Transformations via Insertion of Carbon Dioxide Promoted by Ni-Catalytic Systems

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<p>Carbon dioxide, a greenhouse gas, is among the most important challenges in reducing carbon emissions to reduce global warming. Using carbon dioxide as a carbon resource efficiently requires effective and straightforward synthetic methods for C-C bond transformations. Recently, transition-metal catalyzed coupling reactions of carbon dioxide with soft nucleophiles such as alkynes, conjugated dienes, and a variety of unsaturated hydrocarbons have been studied to provide the corresponding unsaturated carboxylic acids. This article describes the Ni-catalyzed fixation reactions of carbon dioxide with unsaturated hydrocarbons and the highly regio- and stereoselective C-C bond formations promoted by carbon dioxide through nickel carbonate key intermediates.</p>

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