Mechanical Dissolution of Cu₅Zr Phase and Formation of Supersaturated Solid-Solution Nanocrystalline Structure by High-Pressure Torsion in a Hypoeutectic Cu-2.7 at%Zr Alloy
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- Miyamoto Kenta
- Division of Mechanical Science and Engineering, Graduate School of Natural Science and Technology, Kanazawa University
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- Kunimine Takahiro
- Faculty of Mechanical Engineering, Institute of Science and Engineering, Kanazawa University
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- Watanabe Chihiro
- Faculty of Mechanical Engineering, Institute of Science and Engineering, Kanazawa University
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- Monzen Ryoichi
- Faculty of Mechanical Engineering, Institute of Science and Engineering, Kanazawa University
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- Gholizadeh Reza
- Department of Materials Science and Engineering, Kyoto University
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- Tsuji Nobuhiro
- Department of Materials Science and Engineering, Kyoto University
書誌事項
- タイトル別名
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- Mechanical Dissolution of Cu<sub>5</sub>Zr Phase and Formation of Supersaturated Solid-Solution Nanocrystalline Structure by High-Pressure Torsion in a Hypoeutectic Cu–2.7 at%Zr Alloy
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<p>Microstructural evolution and changes in hardness and electrical conductivities of a cast hypoeutectic Cu–2.7 at%Zr alloy processed by high-pressure torsion (HPT) were investigated. The cast alloy had a net-like microstructure composed of a primary Cu phase and a eutectic consisting of layered Cu and Cu5Zr phases. The Cu and Cu5Zr phases in the eutectic had a cube-on-cube orientation relationship. The cast alloy with the hardness of 137 HV exhibited a value of electrical conductivity of 32%IACS. With increasing the number of HPT-revolutions, the eutectic was severely sheared and elongated along the rotational direction. In addition, mechanical dissolution of the Cu5Zr phase into the Cu phase by the HPT was confirmed after 5 HPT-revolutions through XRD measurements and TEM observations. After 20 HPT-revolutions, the Cu phase was significantly refined and formed the lamellar structure having an average grain size of 15 nm. The electrical conductivity decreased and saturated at a value of 8%IACS after 50 HPT-revolutions. The significant decrease in the electrical conductivity was primarily attributable to the mechanical dissolution of the Cu5Zr phase into the Cu phase by the HPT, followed by the formation of a nanocrystalline Cu–Zr supersaturated solid-solution alloy with the hardness of 430 HV.</p><p> </p><p>This Paper was Originally Published in Japanese in J. Japan Inst. Copper 60 (2021) 98–103.</p>
収録刊行物
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- MATERIALS TRANSACTIONS
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MATERIALS TRANSACTIONS 64 (12), 2708-2713, 2023-12-01
公益社団法人 日本金属学会
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詳細情報 詳細情報について
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- CRID
- 1390016803389457024
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- NII書誌ID
- AA1151294X
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- ISSN
- 13475320
- 13459678
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- NDL書誌ID
- 033193550
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可