書誌事項
- タイトル別名
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- Clock reaction behavior in the oxidation polymerization of aniline hydrochloride by the peroxydisulfuric acid in a strong magnetic field.
- アニリン塩酸塩のペルオキソニ硫酸イオンによる時計反応的酸化重合に対する強磁場印加効果
- アニリン エンサンエン ノ ペルオキソニ リュウサン イオン ニ ヨル トケイ ハンノウテキ サンカ ジュウゴウ ニ タイスル キョウジ バ インカ コウカ
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説明
It was made quantitatively clear that the oxidative polymerization process of aniline by S2O82- ion in a highly concentrated hydrochloric acid aqueous solution was a clock reaction. It was strongly dependent on the concentration of S2O82- ion at the start time of the clock reaction. The rate-determining process of the reaction was a one-electron transfer process from C6H5NH2 to S2O82- ion. A possibility was strongly indicated that the strong magnetic field impression effect for this electron-transfer process acted as an inhibitive effect. Moreover, it became clear that the strong magnetic field impression did not influence the formation process of polyanilin. Also, it was indicated that the formation of polyaniline was suppresed by the reaction of the aniline radical with the dissolved oxygen.
収録刊行物
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- 分析化学
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分析化学 51 (10), 907-910, 2002
公益社団法人 日本分析化学会
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キーワード
詳細情報 詳細情報について
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- CRID
- 1390282679029058944
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- NII論文ID
- 10009959168
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- NII書誌ID
- AN00222633
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- COI
- 1:CAS:528:DC%2BD38XotFKntL4%3D
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- NDL書誌ID
- 6316173
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- ISSN
- 05251931
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDLサーチ
- Crossref
- CiNii Articles
- OpenAIRE
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- 抄録ライセンスフラグ
- 使用不可
